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Home/Chemistry/Binary Phase Diagram & Lever Rule

Binary Phase Diagram & Lever Rule

Isomorphous A–B T–x diagram: liquidus, solidus, tie line, and lever-rule phase fractions f_α and f_L for overall composition C₀.

Binary alloy T–x

1100°C
0.4

Schematic isomorphous A–B diagram (like Cu–Ni). In the α+L field the horizontal tie line meets solidus at x_α and liquidus at x_L. Lever rule: f_α = (x_L − C₀)/(x_L − x_α).

Shortcuts

  • •Drag sliders for T and overall composition C₀; the pink probe sits on the isotherm.

Measured values

FieldTwo-phase: α + liquid
T_liquidus(C₀)1163°C
T_solidus(C₀)1067°C
x_α (solidus)0.463
x_L (liquidus)0.296
f_α (lever)0.624
f_L (lever)0.376

About this model

A binary isomorphous phase diagram plots temperature against composition for an A–B alloy that forms a continuous solid solution. The liquidus is the upper boundary of the two-phase α+L field; the solidus is the lower boundary. At a fixed temperature inside that field a horizontal tie line connects the solidus composition x_α to the liquidus composition x_L. For an overall composition C₀ on that tie line the lever rule gives the phase mass fractions f_α = (x_L − C₀)/(x_L − x_α) and f_L = (C₀ − x_α)/(x_L − x_α). The simulator uses a schematic Cu–Ni-like lens diagram so students can move the pink probe and watch the tie line and fraction bar update.

Who it's for: Materials science, metallurgy, physical chemistry, and introductory solidification courses.

Key terms

  • Lever rule
  • Liquidus
  • Solidus
  • Tie line
  • Phase fraction
  • Binary phase diagram

How it works

Binary isomorphous phase diagram with liquidus and solidus curves. Set temperature and overall composition to see the tie line in the two-phase field and compute solid/liquid fractions with the lever rule.

Key equations

Tie line at T: solidus → x_α(T), liquidus → x_L(T)
f_α = (x_L − C₀)/(x_L − x_α) · f_L = (C₀ − x_α)/(x_L − x_α)
f_α + f_L = 1 (mass fractions of phases)

Frequently asked questions

Why is it called the lever rule?
The overall composition is the fulcrum of a lever whose arms are the distances to the phase compositions on the tie line. The longer arm opposite a phase means that phase has the smaller fraction — just like a mechanical lever.
Do f_α and f_L always sum to one?
Yes for mass (or mole) fractions of the two coexisting phases in a closed binary system at equilibrium. Outside the two-phase field one fraction is 1 and the other is 0.